A chelate-amidozirconium fragment as building block for unsupported trinuclear ZrM2 heterobimetallic complexes (M = Fe, Ru, Co)

Friedrich, Stefan and Gade, Lutz H. and Scowen, Ian J. and McPartlin, Mary (1996) A chelate-amidozirconium fragment as building block for unsupported trinuclear ZrM2 heterobimetallic complexes (M = Fe, Ru, Co). Angewandte Chemie (International Edition in English), 35 (12). pp. 1338-1341. ISSN 0570-0833

Full content URL: http://dx.doi.org/10.1002/anie.199613381

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Item Type:Article
Item Status:Live Archive

Abstract

Exclusive mono-insertion into one of the polar metal–metal bonds is an apt description of the reaction of thermally stable ZrFe2 and ZrRu2 complexes 1 with methyl isocyanide [Eq. (a); M = Fe, Ru]. Thus surprisingly, the second of the two polar ZrM bonds in 1 as well as the distorted tetrahedral coordination geometry of the Zr atom remain intact. The low degree of steric congestion in 1 is manifest in a rapid rotation about the ZrM bonds that cannot be frozen out even on cooling to 180 K.

Additional Information:Became Angewandte Chemie - International Edition (1433-7851 / 1521-3773) in 1997
Keywords:Chemistry
Subjects:F Physical Sciences > F100 Chemistry
Divisions:College of Science > School of Chemistry
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ID Code:13095
Deposited On:19 Mar 2014 17:49

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