Titanium and zirconium complexes containing a novel dianionic trifunctional amido ligand

Friedrich, S. and Schubart, M. and Gade, L. H. and Scowen, I. J. and Edwards, A. J. and McPartlin, M. (1997) Titanium and zirconium complexes containing a novel dianionic trifunctional amido ligand. Chemische Berichte, 130 (12). pp. 1751-1759. ISSN 0009-2940

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Item Type:Article
Item Status:Live Archive

Abstract

The novel tridentate diamidoamine ligands RC(2-C5H4N)(CH2NSiMe3) 22- (R = H, CH3) have been synthesized and coordinated to TiIV and ZrIV giving the pentacoordinate complexes MX2(RC(2-C5H4N)(CH2NSiMe 3)2 (M = Ti, Zr; X = Cl, Br). The crystal structure analysis of TiBr2(HC(2-C5H4N)(CH2NSiMe 3)

Additional Information:European Journal of Inorganic Chemistry
Keywords:Amido complexes, Titanium, Zirconium, Alkylmetal compounds
Subjects:F Physical Sciences > F120 Inorganic Chemistry
Divisions:College of Science > School of Chemistry
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ID Code:13090
Deposited On:18 Aug 2015 13:55

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