Metal-ion-directed synthesis of sulfur-based macrocyclic helicates

Matthews, R. W. and McPartlin, M. and Scowen, I. J. (1997) Metal-ion-directed synthesis of sulfur-based macrocyclic helicates. Journal of the Chemical Society - Dalton Transactions (17). pp. 2861-2863. ISSN 0300-9246, 1477-9226

Full content URL: http://dx.doi.org/10.1039/A704691J

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Item Type:Article
Item Status:Live Archive

Abstract

Schiff-base condensation of pyridine-2,6-dicarbaldehyde and 2-(2-{(2-aminophenyl)sulfanyl]methyl}benzyl)sulfanyl]aniline led to different helical macrocyclic products depending on the template metal ion; a mono-helical 1 + 1 macrocyclic complex was generated in the presence of AgI and a double-helical 2 + 2 macrocyclic complex was generated in the presence of CdII.

Keywords:Chemistry
Subjects:F Physical Sciences > F100 Chemistry
Divisions:College of Science > School of Chemistry
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ID Code:13084
Deposited On:19 Mar 2014 17:53

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