Ligand exchange and molecular aggregation of an Ag-Sn heterobimetallic complex: first structural characterization of an Ag-Sn bond

Findels, Bernd and Gade, Lutz H. and Scowen, Ian J. and McPartlin, Mary (1997) Ligand exchange and molecular aggregation of an Ag-Sn heterobimetallic complex: first structural characterization of an Ag-Sn bond. Inorganic Chemistry, 36 (6). pp. 960-961. ISSN 0020-1669

Full content URL: http://dx.doi.org/10.1021/ic9611352

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Item Type:Article
Item Status:Live Archive

Abstract

A direct Ag−Sn bond has been established for the first time by X-ray crystallography for the dimeric complex [MeSi{SiMe2N(p-Tol)}3SnAg]2 (4) [d(Ag−Sn) =2.6567(7) Å], which is the product of a phosphine ligand redistribution reaction of MeSi{SiMe2N(p-Tol)}3SnAg(PPh3) (2).

Keywords:Chemistry
Subjects:F Physical Sciences > F100 Chemistry
Divisions:College of Science > School of Chemistry
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ID Code:13083
Deposited On:19 Mar 2014 18:56

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