Highly selective trimerisation of MeNC by a novel titanium imido complex containing a tridentate dianionic ligand

Blake, Alexander J. and Collier, Philip E. and Gade, Lutz H. and McPartlin, Mary and Mountford, Philip and Schubart, Martin and Scowen, Ian J. (1997) Highly selective trimerisation of MeNC by a novel titanium imido complex containing a tridentate dianionic ligand. Chemical Communications (16). pp. 1555-1556. ISSN 1359-7345

Full content URL: http://dx.doi.org/10.1039/A703275G

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Item Type:Article
Item Status:Live Archive

Abstract

A new type of imido compound Ti(NBut)L(py) 1 containing a tripodal dianionic ligand is reported which effects the remarkably selective trimerisation of MeNC; the crystal structures of 1 and TiL{N(Me)N(But)(C4H3N2Me)} 2 are described L = MeC(2-C5H4N)(CH2NSiMe3) 2.

Keywords:Chemistry
Subjects:F Physical Sciences > F100 Chemistry
Divisions:College of Science > School of Chemistry
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ID Code:13082
Deposited On:19 Mar 2014 19:41

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