Cooperative reactivity of unsupported early-late heterobimetallics: Ring opening and subsequent decarbonylation of biaryllactones

Schneider, A. and Gade, L. H. and Breuning, M. and Bringmann, G. and Scowen, I. J. and McPartlin, M. (1998) Cooperative reactivity of unsupported early-late heterobimetallics: Ring opening and subsequent decarbonylation of biaryllactones. Organometallics, 17 (9). pp. 1643-1645. ISSN 0276-7333

Full content URL: http://dx.doi.org/10.1021/om980007d

Full text not available from this repository.

Item Type:Article
Item Status:Live Archive

Abstract

Reaction of the heterodinuclear complex HC-{SiMe2N(2-FC6H3)}3Zr-FeC p(CO)2 (1) with 1,3-di-methyl-6H-benzobnaphtho1,2-dpyranone (2) and 1,3-dimethoxy-6H-benzob-naphtho-1,2-dpyranone (3) led to immediate ring opening of the lactones to yield products which combine the biaryl fragment with aryloxyzirconium and acyl-FeCp(CO)2 units. The latter slowly decarbonylate to yield the corresponding heterobimetallic complexes in which the {MCp(CO)2} fragment is directly bonded to the naphthalene ring.

Additional Information:Publication Date (Web): April 09, 1998 (Communication)
Keywords:Chemistry
Subjects:F Physical Sciences > F100 Chemistry
Divisions:College of Science > School of Chemistry
Related URLs:
ID Code:13076
Deposited On:19 Mar 2014 19:11

Repository Staff Only: item control page