Ligand control of molecular helicity in the coordination of toxic heavy metal ions: crystal structure of a monohelical cadmium(II) complex

Beynek, Nesrin and McPartlin, Mary and Murphy, Brian P. and Scowen, Ian J. (1998) Ligand control of molecular helicity in the coordination of toxic heavy metal ions: crystal structure of a monohelical cadmium(II) complex. Polyhedron, 17 (11-12). pp. 2137-2140. ISSN 0277-5387

Full content URL: http://dx.doi.org/10.1016/S0277-5387(97)00472-5

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Item Type:Article
Item Status:Live Archive

Abstract

The new semi-rigid diimine ligand, OpyNpy2, coordinates the toxic heavy metals ions Cd(II) and Hg(II) in a monohelical fashion, as established, in the former, by X-ray crystallography and, in both, by 1H NMR spectroscopy; ligand control is attributed to the helical topology of these complexes of stereochemically non-demanding ions. © 1998 Elsevier Science Ltd. All rights reserved.

Keywords:Ligand, Monohelical, Cadmium (II) complex
Subjects:F Physical Sciences > F100 Chemistry
Divisions:College of Science > School of Chemistry
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ID Code:13071
Deposited On:19 Mar 2014 17:50

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