Ionic cleavage of Ti-Co and Zr-Co bonds: the role of the nucleophilicity of the late transition metal in the reactive behaviour of early-late heterobimetallics

Schubart, Martin and Mitchell, Gemma and Kottke, Thomas and Gade, Lutz H. and Scowen, Ian J. and McPartlin, Mary (1999) Ionic cleavage of Ti-Co and Zr-Co bonds: the role of the nucleophilicity of the late transition metal in the reactive behaviour of early-late heterobimetallics. Chemical Communications (3). pp. 233-234. ISSN 1359-7345

Full content URL: http://dx.doi.org/10.1039/A808498J

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Item Type:Article
Item Status:Live Archive

Abstract

The ionic cleavage of Ti-Co and Zr-Co bonds occurs upon reaction with Bu(t)NC and the products MeSi{SiMe2N(p-Tol)}3Ti(CNBu(t))2lCo(CO)4] 3 and MeSi{SiMe2N(p-Tol)}3Zr(CNBu(t))3Co(CO)4 4 were characterized by single crystal X-ray diffraction; the importance of the nucleophilicity of the late transition metal fragment in reactions of the unsupported early-late heterobimetallics is demonstrated.

Keywords:cobalt, titanium, zirconium, article, chemical bond
Subjects:F Physical Sciences > F100 Chemistry
Divisions:College of Science > School of Chemistry
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ID Code:13068
Deposited On:19 Mar 2014 19:40

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