Atom-transfer within the coordination sphere of early-late heterobimetallic complexes: rapid deoxygenation of sulfoxides at low temperatures

Fabre, Sylvie and Findeis, Bernd and Trosch, Dominique J. M. and Gade, LutzH. and Scowen, Ian J. and McPartlin, Mary (1999) Atom-transfer within the coordination sphere of early-late heterobimetallic complexes: rapid deoxygenation of sulfoxides at low temperatures. Chemical Communications (7). pp. 577-578. ISSN 1359-7345

Full content URL: http://dx.doi.org/10.1039/A900010K

Full text not available from this repository.

Item Type:Article
Item Status:Live Archive

Abstract

Extremely rapid oxygen transfer from sulfoxides to a carbonyl ligand to give the corresponding thioether and coordinated CO2 is observed in the reactions of unsupported Zr-Ru heterodimetallic complexes with sulfoxides; this is interpreted to arise from the cooperative reactivity of the two complementary metal complex fragments bound to each other through a highly polar metal-metal bond.

Keywords:carbon dioxide, carbonyl derivative, metal complex, oxygen, rubidium, sulfide, sulfoxide, zirconium derivative, article, atom, chemical bond, chemical reaction, chemical structure, low temperature
Subjects:F Physical Sciences > F100 Chemistry
Divisions:College of Science > School of Chemistry
Related URLs:
ID Code:13067
Deposited On:19 Mar 2014 19:34

Repository Staff Only: item control page