C-C and C-N coupling reactions of an imidotitanium complex with isocyanides

Bashall, A. and Collier, P. E. and Gade, L. H. and McPartlin, M. and Mountford, P. and Pugh, S. M. and Radojevic, S. and Schubart, M. and Scowen, I. J. and Trosch, D. J. M. (2000) C-C and C-N coupling reactions of an imidotitanium complex with isocyanides. Organometallics, 19 (23). pp. 4784-4794. ISSN 0276-7333

Full content URL: http://dx.doi.org/10.1021/om0005710

Full text not available from this repository.

Item Type:Article
Item Status:Live Archive

Abstract

Reaction of the imidotitanium complex (k3-N2Npy)Ti(=NtBu)(py) (1) N2Npy = (2-C5H4N)C(Me)(CH2NSiMe3) 2 with 2,6-xylylisocyanide led to double insertion of the isocyanide into the imidotitanium bond and yielded the four-membered titanacycle (k3-N2Npy)Ti-{N(tBu)C(=N-2,6-Me2C 6H3)C(=N-2,6-C6H3Me2)} (2), which was characterized by X-ray crystallography. © 2000 American Chemical Society.

Additional Information:Publication Date (Web): October 21, 2000
Keywords:Chemistry
Subjects:F Physical Sciences > F100 Chemistry
Divisions:College of Science > School of Chemistry
Related URLs:
ID Code:13061
Deposited On:19 Mar 2014 19:11

Repository Staff Only: item control page