A synthesis of carbasugar-sugar pseudodisaccharides via a cycloaddition-cycloreversion reaction of 2 H-Pyran-2-ones

Afarinkia, Kamyar and Abdullahi, Mohamed Haji and Scowen, Ian J. (2010) A synthesis of carbasugar-sugar pseudodisaccharides via a cycloaddition-cycloreversion reaction of 2 H-Pyran-2-ones. Organic Letters, 12 (23). pp. 5564-5566. ISSN 1523-7060

Full content URL: http://dx.doi.org/10.1021/ol102358s

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Item Type:Article
Item Status:Live Archive

Abstract

Cycloaddition of 3-carbomethoxy-2H-pyran-2-one to a vinylated sugar followed by the loss of bridging CO2 from the cycloadduct affords a cyclohexadiene which can be manipulated to a carbasugar-sugar pseudodisaccharide. © 2010 American Chemical Society.

Keywords:carbasugar, disaccharide, hydrogen, pyran derivative, article, chemical structure, chemistry, cyclization, synthesis, Carbasugars, Disaccharides, Molecular Structure, Pyrans
Subjects:F Physical Sciences > F100 Chemistry
Divisions:College of Science > School of Chemistry
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ID Code:13026
Deposited On:19 Mar 2014 17:50

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